I admit, I do try to gather scalps. First day the Zephyr came out, I performed my first ever suicide gank by downing one at a grav in Hek. So when I saw a Venture mining recently in Frerstorn, I went in for the kill in my Vengeance.
Of course, the guy in the Rapier was ahead of me on this one, having thought to himself "Surely some prosuf PVPer in lowsec will want a Venture killmail. I shall cloak off my alt and fuck him up."
Yes indeed, I should have done this in something a bit cheaper. But a 30M ISK Vengeance loss to put a Venture scalp on my saddlehorn? Worth it.